Bismuth

Bi 4f7/2 binding energy data collated from [1].
Bi 4f7/2 - 4f5/2 splitting: 5.31 eV [2]
Bi 4d5/2: 440 eV
Bi 4d3/2: 464 eV
Bi 4p3/2: 679 eV
Bi 4p1/2: 806 eV
Bi 4s: 940 eV
Bi 5d5/2: 24 eV
Bi 5d3/2: 27 eV
Bi 5p3/2: 93 eV
Bi 5p1/2: 119 eV
Bi 5s: 161 eV

Kratos R.S.F. Bi 4f = 9.14, Bi 4f7/2 = 5.223

Reference:
[1] C.D. Wagner, A.V. Naumkin, A. Kraut-Vass, J.W. Allison, C.J. Powell, J.R.Jr. Rumble, NIST Standard Reference Database 20, Version 3.4 (web version) (http:/srdata.nist.gov/xps/) 2003.
[2] J.F. Moulder, W.F. Stickle, P.E. Sobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corp, Eden Prairie, MN, 1992.